| 高沸醇木质素环氧树脂的合成与性能研究 |
| |
| 引用本文： | 林玮,程贤甦.高沸醇木质素环氧树脂的合成与性能研究[J].纤维素科学与技术,2007,15(2):8-12,16. |
| |
| 作者姓名： | 林玮 程贤甦 |
| |
| 作者单位： | 1. 福州大学材料科学与工程学院,福建,福州,350002
2. 福州大学材料科学与工程学院,福建,福州,350002;闽江学院化学与化学工程系,福建,福州,350011 |
| |
| 基金项目： | 福建省经贸委科研项目;福建省福州市特殊人才引进基金 |
| |
| 摘 要： | 利用高沸醇木质素的化学活性,直接与环氧氯丙烷反应,生成木质素环氧树脂和木质素改性双酚A型环氧树脂,用环氧值、红外光谱、TGA和DSC等对树脂进行表征,并与未改性的双酚A型环氧树脂进行对比。结果表明,高沸醇木质素很容易合成木质素环氧树脂,其最佳合成条件是:n(ECH)∶n(-OH)=8,温度55～60℃,碱浓度为5%;高沸醇木质素环氧树脂能显著提高环氧树脂的耐溶剂性和耐热性。
|
| 关 键 词： | 高沸醇木质素环氧树脂 木质素改性双酚A型环氧树脂 耐溶剂性 耐热性 |
| 文章编号： | 1004-8405(2007)02-0008-06 |
| 修稿时间： | 2006年3月27日 |
Study on Synthesis and Properties of HBS Lignin Epoxy Resins |
| |
| LIN Wei,CHENG Xian-su.Study on Synthesis and Properties of HBS Lignin Epoxy Resins[J].Journal of Cellulose Science and Technology,2007,15(2):8-12,16. |
| |
| Authors: | LIN Wei CHENG Xian-su |
| |
| Abstract: | High boiling solvents(HBS) lignin epoxy resin and HBS lignin-modified bisphenol-A epoxy resins were successfully synthesized with HBS lignin,a novel eco-material,whose chemical reactivity is high.These resins were characterized by epoxy value,IR spectra,TGA and DSC,etc,and compared with pure bisphenol-A epoxy resin.The results showed that HBS lignin could directly react with epichlorohydrin to form epoxy resins,the best reaction conditions for which were n(ECH)∶n(-OH)=8,temperature 55～60℃ and catalyst concentration 5% by weight,and that modification with HBS lignin remarkably improved the properties of solvent resistance and heat resistance. |
| |
| Keywords: | high boiling solvents(HBS) lignin epoxy resin HBS lignin-modified bisphenol-A epoxy resin solvent resistance heat resistance |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
