Semiconduction properties of some polyene-iodine charge-transfer complexes and their application in solid-state batteries

The conjugated polyenes -carotene, lutein, retinoic acid and -apo-8-carotenal are shown to form charge-transfer (CT) complexes with the electron acceptor iodine. The conductivity increases by several orders of magnitude and the activation energy decreases on CT complex formation. Using these complexes as cathodic material, batteries with the configuration Mg/(polyene-iodine CT complex) /graphite are developed. Different battery parameters are evaluated. The effects of ambient temperature and humidity on battery performance are also studied. Results show that a -apo-8-carotenal-l₂ based battery has the maximum power density and longest self-life and is suitable for use as a micro-electronic gadget energizer.