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Novel nanocellulosic xylan composite film
Authors:Amit Saxena   Thomas J. Elder   Shaobo Pan  Arthur J. Ragauskas  
Affiliation:aSchool of Chemistry and Biochemistry, Georgia Institute of Technology, 500 10th St., Atlanta, GA 30332, USA;bUSDA–Forest Service, Southern Research Station, 2500 Shreveport Highway, Pineville, LA 71360, USA;cChalmers University of Technology, Forest Products and Chemical Engineering, Kemivägen 10, Gothenburg SE-412 96, Sweden
Abstract:Nanocellulosic-xylan films were prepared employing oat spelt xylan, cellulose whiskers and a plasticizer. The mechanical properties of the films were evaluated using tensile testing under controlled temperature and humidity conditions. The tensile data showed that the addition of sulfonated cellulose whiskers lead to a substantial improvement in strength properties. Addition of 7 wt% of sulfonated whiskers increased the tensile energy absorption of xylan films by 445% and the tensile strength of the film by 141%. Furthermore, films to which 7% cellulose whiskers were added showed that nanocellulose whiskers produced with sulfuric acid (sulfonated whiskers) were significantly better at increasing film strength than cellulose whiskers produced by hydrochloric acid hydrolysis of cellulosic fibers.
Keywords:A. Xylan   A. Film   A. Cellulose whiskers   B. Strength   A. Nanocomposites
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