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磷酸制种生产超细氢氧化铝的新工艺研究
引用本文:李民菁,史智慧,吴利彬,孙克晗,翟福霞. 磷酸制种生产超细氢氧化铝的新工艺研究[J]. 轻金属, 2011, 0(7)
作者姓名:李民菁  史智慧  吴利彬  孙克晗  翟福霞
作者单位:河南未来铝业(集团)有限公司,河南焦作,454171
摘    要:本工艺打破了只有用烧结法精液生产超细氢氧化铝的桎梏,充分利用磷对分解加速和加深的影响,磷酸三钠的分散性能,用便宜的拜耳法精液为生产原料,精制成脱色精液,用磷酸制备高活性晶种浆液进行两段分解。中试结果表明,本工艺生产成本低,制晶种易控制,晶型结构完整,产品分散效果、洗涤性能良好,一段、二段分解率达到70%~75%和65%~70%,磷可以以磷酸钙进入赤泥,从而消除了磷的累积影响。

关 键 词:拜耳法  磷酸  活性晶种  超细氢氧化铝  分散剂  

A research about the production of ultra-fine aluminum hydroxide with the active seed cystal by phosphorylation
LI Min-jing,SHI Zhi-hui,WU Li-bin,SUN Ke-han,ZHAI Fu-xia. A research about the production of ultra-fine aluminum hydroxide with the active seed cystal by phosphorylation[J]. Light Metals, 2011, 0(7)
Authors:LI Min-jing  SHI Zhi-hui  WU Li-bin  SUN Ke-han  ZHAI Fu-xia
Affiliation:LI Min-jing,SHI Zhi-hui,WU Li-bin,SUN Ke-han and ZHAI Fu-xia(Henan Weilai Aluminium Industry(Group)Co.,Ltd.,Jiaozuo 454171,China)
Abstract:This process has broken the shackles of producing super-fine aluminium hydroxide only by the sintering process of green liquor.It has made full use of phosphorous hastening decomposition as well as dispersing function of trisodium orthophosphate to produce decolored green liquor with cheap Baier green liquor as material and achieved two sections of decomposition with the help of active seed crystal liquid.The results of the experiment show that the process of production costs low and is easy to control,crys...
Keywords:Bayer method  phosphoric acid  active seed crystal  super-fine aluminum hydroxide  dispersing agents  
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