Development of a Four-Channel Potentiostat for Amperometric Detection in Flow Injection Analysis

Abstract

A four-channel multipotentiostat has been developed for simultaneous voltammetric measurements with microelectrode arrays. To reduce the complexity of electrochemical cell, only one reference and one auxiliary electrode are used. The potential ranges of the four working electrodes may be independently controlled, but they are synchronously scanned by only one DAC. This is accomplished through a microcomputer interfaced with a PCL-711B data acquisition board, which allows the continuous monitoring of the currents and actual potentials of the working electrodes.

The system has been applied to the simultaneous determination of ascorbic and uric acids in synthetic samples. The measurements were carried out with gold microelectrodes modified by deposition of noble metals, which enhance the electrocatalysis and provide an anticipation and a better definition of the oxidation potentials. Recuperation of 98.2% and 97.8% for ascorbic and uric acids, respectively, was obtained by using amperometry.