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掺Eu3+, Sm3+, Tb3+的TTFA配合物敏化发光效应的实验研究
引用本文:许思友,葛文萍,王磊,何蕾. 掺Eu3+, Sm3+, Tb3+的TTFA配合物敏化发光效应的实验研究[J]. 激光技术, 2008, 32(6): 579-581
作者姓名:许思友  葛文萍  王磊  何蕾
作者单位:1.新疆大学, 物理科学与技术学院, 乌鲁木齐, 830046;
基金项目:中国科学院西部之光人才培养计划基金  
摘    要:为了研究稀土离子的α-噻吩甲酰三氟丙酮(α-thienyltrifluoroacetone,TTFA)配合物中敏化发光效应,对自行制备出的稀土离子Eu3+,Sm3+和Tb3+单掺TTFA配合物Eu(TTFA)3,Tb(TTFA)3,Sm(TTFA)3及3种稀土离子两两共掺的配合物的荧光光谱进行了分析,得出了稀土离子Eu3+,Sm3+,Tb3+与配体TTFA的敏化特性以及稀土离子Eu3+,Sm3+和Tb3+之间的敏化特性。Eu(TTFA)3,Tb(TTFA)3,Sm(TTFA)3及3种稀土离子共掺的配合物中,稀土离子Eu3+,Sm3+,Tb3+与配体TTFA及Eu3+,Sm3+,Tb3+之间有明显的敏化效应。结果表明,将其用于聚合物光纤放大器具有良好的发展前景。

关 键 词:光纤光学   敏化效应   聚合光纤   稀土离子
收稿时间:2007-10-24

Experimental research of the sensitization effect of Eu~(3+),Sm~(3+),Tb~(3+) and TTFA polymers
XU Si-you,GE Wen-ping,WANG Lei,HE Lei. Experimental research of the sensitization effect of Eu~(3+),Sm~(3+),Tb~(3+) and TTFA polymers[J]. Laser Technology, 2008, 32(6): 579-581
Authors:XU Si-you  GE Wen-ping  WANG Lei  HE Lei
Affiliation:XU Si-you1,GE Wen-ping2,WANG Lei1,HE Lei1(1.College of Physics Science & Technology,Xinjiang University,Urumuqi 830046,China,2.College of Information Science , Engineering,China)
Abstract:In order to study the sensitization effect of Eu3+,Sm3+,Tb3+ and α-thienyltrifluoroacetone(TTFA)polymers,rare earth complex-doped polymers and rare earth ions complex-co doped polymers was made from the rare earth ions Eu3+,Sm3+,Tb3+and TTFA. The fluorescence properties of these chelate complexes in ethanol were investigated. Sensitization effect properties of rare earth complex-doped polymers and rare earth ions complex-co doped polymers were found. The study results can be used in polymer optical fiber amplifiers with good development.
Keywords:fiber optics  sensitization effect  polymer optical fiber  rare earth ions  
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