Preparation and Properties of Sodium, Potassium, Magnesium, Calcium, and Aluminum Terephthalates |
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| Authors: | G P Panasyuk L A Azarova Mishal Khaddaj G P Budova I L Voroshilov T V Grusha A D Izotov |
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| Affiliation: | (1) Russian Academy of Sciences, Kurnakov Institute of General and Inorganic Chemistry, Leninskii pr. 31, Moscow, 119991, Russia |
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| Abstract: | Group I–III terephthalates were prepared: KOOCC6H4COOH, NaOOCC6H4COOH, NaOOCC6H4COONa, Mg(OOCC6H4COO) · 2H2O, Ca(OOCC6H4COO) · 3H2O, and Al2(OOCC6H4COO)3 · 8H2O. The salts were characterized by differential thermal analysis and IR spectroscopy. The results demonstrate that the thermal decomposition of the terephthalates yields metal carbonates or oxides. On heating to 1000°C, aluminum terephthalate converts into submicron-sized  -alumina particles. |
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