| 金属-有机络合聚合物(MOCPs)的研究进展 |
| |
| 引用本文： | 杨明莉,武凯,鲜学福. 金属-有机络合聚合物(MOCPs)的研究进展[J]. 功能材料, 2006, 37(11): 1697-1699,1702 |
| |
| 作者姓名： | 杨明莉 武凯 鲜学福 |
| |
| 作者单位： | 西南资源开发及环境灾害控制教育部重点实验室,重庆,400044;西南资源开发及环境灾害控制教育部重点实验室,重庆,400044 |
| |
| 摘 要： | 从配体的角度对中心离子与多齿配体间形成的稳定多孔金属-有机络合聚合物(MOCPs)的发展现状进行了综述.指出该材料自成为研究热点以来,各研究小组在对不同的构件分子进行组合构建新的MOCPs方面富有成效的工作,极大地丰富了络合聚合物的结构数据,但这种材料最引人注目的特性--孔及表面性质的可调控性及其对其各种应用特性,如分子识别、择形催化、择形吸附等所能带来的影响方面的研究还很不够.
|
| 关 键 词： | 多孔固体 金属-有机骨架 金属-有机络合聚合物 吸附 气体储存 |
| 文章编号： | 1001-9731（2006）11-1697-03 |
| 收稿时间： | 2006-04-07 |
| 修稿时间： | 2006-04-072006-06-21 |
Progress in porous metal-organic coordination polymers |
| |
| YANG Ming-li,WU Kai,XIANG Xue-fu. Progress in porous metal-organic coordination polymers[J]. Journal of Functional Materials, 2006, 37(11): 1697-1699,1702 |
| |
| Authors: | YANG Ming-li WU Kai XIANG Xue-fu |
| |
| Affiliation: | 1. Key Lab. for the Exploitation of Southwestern Resources and the Environmental Disaster Control Engineering, Ministry of Education,Chongqing 400044,China; 2. College of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400044,China |
| |
| Abstract: | The current progress in porous metal-organic coordination polymers(MOCPs)built by the chelate bonds between center metal ions and ligands is reviewed according to the ligand types in this paper.It is pointed out that a lot of structure data have been accumulated by many research groups through their efficient jobs in the MOCPs synthesis since the materials became a hotspot in 1990s,but there is some shortage in the research of the relationship between the regulable superiority in pore structure and their applied properties,like molecu- lar identification,shape-selecting adsorption or catalysis,etc.And the structure-effect relations are just the most remarkable of the materials. |
| |
| Keywords: | porous solids metal-organic coordination polymers metal-organic frameworks adsorption gas storage |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
