| 缩聚表面接枝纳米SiO2改性PBT |
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| 引用本文： | 栾宝勇,车剑飞,董晓明,杨绪杰,陆路德,汪信.缩聚表面接枝纳米SiO2改性PBT[J].合成树脂及塑料,2005,22(1):44-47. |
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| 作者姓名： | 栾宝勇 车剑飞 董晓明 杨绪杰 陆路德 汪信 |
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| 作者单位： | 南京理工大学材料化学实验室,江苏,南京,210094;南京理工大学材料化学实验室,江苏,南京,210094;南京理工大学材料化学实验室,江苏,南京,210094;南京理工大学材料化学实验室,江苏,南京,210094;南京理工大学材料化学实验室,江苏,南京,210094;南京理工大学材料化学实验室,江苏,南京,210094 |
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| 基金项目： | 江苏省科委重点攻关项目(BG2002015). |
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| 摘 要： | 通过缩聚在纳米SiO2粒子表面接枝低聚物并对其改性，采用红外光谱、热失重、透射电子显微镜对接枝改性后的纳米SiO2进行了测试。将得到的改性粒子填充聚对苯二甲酸丁二醇酯，检测填充前后树脂的性能。结果表明，填充后的树脂流动性能得到改善，拉伸强度、断裂伸长率提高，ω(SiO2)的最佳值为2．0％。
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| 关 键 词： | 聚对苯二甲酸丁二醇酯 纳米二氧化硅 缩聚 表面改性 |
| 文章编号： | 1002-1396(2005)01-0044-04 |
| 修稿时间： | 2004年8月5日 |
Study on surface modification of PBT with grafted nano-SiO2 by polycondensation |
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| Luan Baoyong,Che Jianfei,Dong Xiaoming,Yang Xujie,Lu Lude,Wang Xin.Study on surface modification of PBT with grafted nano-SiO2 by polycondensation[J].China Synthetic Resin and Plastics,2005,22(1):44-47. |
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| Authors: | Luan Baoyong Che Jianfei Dong Xiaoming Yang Xujie Lu Lude Wang Xin |
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| Abstract: | The prepolymer of polybutylene terephthalate (PBT) was grafted onto the surface of nano-SiO2 partides by polycondensation for modification. The particles so treated were characterized by infrared spectroscopy, thermogravimetry and transmission electron microscopy. The nano-SiO2 particles were filled into PBT and the performance of PBT pre-and post-filling was determined. The result shows that the flowability of PBT is improved, and its tensile strength and elongation at break is raised. The optim filling mass fraction of nano- SiO2 is 2.0%. |
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| Keywords: | polybutylene terephthalate nano-SiO2 polycondensation surface modification |
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