| 电沉积制备稀土填充热电材料CoSb3Smx工艺条件探索 |
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| 引用本文： | 田鹏,陈桂强,周智,龚晓钟. 电沉积制备稀土填充热电材料CoSb3Smx工艺条件探索[J]. 广东化工, 2009, 36(12): 5-6,10 |
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| 作者姓名： | 田鹏 陈桂强 周智 龚晓钟 |
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| 作者单位： | 深圳大学,化学与化工学院,深圳市功能高分子重点实验室,广东,深圳,518060;中国进出口检验检疫局,工业品检测技术中心,广东,深圳,518045 |
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| 基金项目： | 国家自然科学基金资助项目(50371058)，广东省自然科学基金资助项目(04011311)，广东省科技计划项目，深圳市基金资助项目 |
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| 摘 要： | 在室温条件下于非水体系中用电沉积的方法制备Sm填充方钴矿化合物。研究制备稀土填充的方钴矿CoSb3热电材料的最佳工艺条件。在最佳工艺条件下稀土元素达到最大填充量，合金薄膜的组成为Smo32CoSb3。
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| 关 键 词： | 脉冲电沉积 填充式方钴矿 稀土元素 热电材料 非水体系 |
Electrodeposition and Characterization of Rare-earth Element Filled Thermoelectric Material CoSb_3Sm_x |
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| Tian Peng,Chen Guiqiang,Zhou Zhi,Gong Xiaozhong. Electrodeposition and Characterization of Rare-earth Element Filled Thermoelectric Material CoSb_3Sm_x[J]. Guangdong Chemical Industry, 2009, 36(12): 5-6,10 |
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| Authors: | Tian Peng Chen Guiqiang Zhou Zhi Gong Xiaozhong |
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| Affiliation: | Tian Peng1,Chen Guiqiang2,Zhou Zhi1,Gong Xiaozhong1(1.College of Chemistry and Chemical Engineering,Shenzhen University,Shenzhen Key Laboratory of Functional Polymers,Shenzhen 518060,2.College of Material,Shenzhen Key Laboratory of Special Functional Materials,Shenzhen 518045,China) |
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| Abstract: | Sm-filled Skutterudite was prepared in ionic liquids by electrodeposition at room temperature.The best processing conditions of preparing different Rare-Earth Element Filled Skutterudite was studied.Scanning electron microscopy(SEM) and energy dispersive spectrometer(EDX) were employed to characterize the morph-ologies.The Composition of alloy thin film is Sm0.32CoSb3.The CoSb3 is body-centered cubic,the Co2Sm5 is monoclinic. |
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| Keywords: | pulsed electrodeposition filled-Skutterudite rare-Earth Element thermoelectric material ionic liquids |
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