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利用受限空间装置从低浓度水包油乳状液中分离油相的研究(英文)
引用本文:王硕,秦炜,戴猷元.利用受限空间装置从低浓度水包油乳状液中分离油相的研究(英文)[J].中国化学工程学报,2012,20(2):239-245.
作者姓名:王硕  秦炜  戴猷元
作者单位:State Key Laboratory of Chemical Engineering, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China
基金项目:Supported by the Eleventh Five-Year Plan of national support (2007BAI26B03-04)
摘    要:A miniature process for separating the oil phase from dilute oil/water emulsion is developed.This process applies a confined space apparatus,which is a thin flow channel made of two parallel plastic plates.The space between the two plates is rather narrow to improve the collisions between oil droplets and the plate surface.Oil droplets have an affinity for the plate surface and thus are captured,and then coalesce onto the surface.The droplet size distribution of the residual emulsion resulted from the separation process is remarkably changed.The oil layer on the plate weakens the further separation of oil droplets from the emulsion.Three types of plate materials,polypropylene(PP),polytetrafluoroethylene(PTFE) and nylon 66,were used.It is found that PP is the best in terms of the oil separation efficiency and nylon 66 is the poorest.The interaction between droplets in the emulsion and plate surface is indicated by the spreading coefficient of oil droplet on the plate in aqueous environment,and the influences of formed oil layer and plate material on the separation efficiency are discussed.

关 键 词:oil/water  emulsion  confined  space  apparatus  oil  separation  efficiency  spreading  coefficient  
收稿时间:2011-07-24

Separation of Oil Phase from Dilute Oil/Water Emulsion in Confined Space Apparatus
WANG Shuo,QIN Wei and DAI Youyuan.Separation of Oil Phase from Dilute Oil/Water Emulsion in Confined Space Apparatus[J].Chinese Journal of Chemical Engineering,2012,20(2):239-245.
Authors:WANG Shuo  QIN Wei and DAI Youyuan
Affiliation:State Key Laboratory of Chemical Engineering, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China
Abstract:A miniature process for separating the oil phase from dilute oil/water emulsion is developed.This process applies a confined space apparatus,which is a thin flow channel made of two parallel plastic plates.The space between the two plates is rather narrow to improve the collisions between oil droplets and the plate surface.Oil droplets have an affinity for the plate surface and thus are captured,and then coalesce onto the surface.The droplet size distribution of the residual emulsion resulted from the separation process is remarkably changed.The oil layer on the plate weakens the further separation of oil droplets from the emulsion.Three types of plate materials,polypropylene(PP),polytetrafluoroethylene(PTFE) and nylon 66,were used.It is found that PP is the best in terms of the oil separation efficiency and nylon 66 is the poorest.The interaction between droplets in the emulsion and plate surface is indicated by the spreading coefficient of oil droplet on the plate in aqueous environment,and the influences of formed oil layer and plate material on the separation efficiency are discussed.
Keywords:oil/water emulsion  confined space apparatus  oil separation efficiency  spreading coefficient
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