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Na_(1/2)Bi_(1/2)TiO_3基无铅压电体系退极化行为的研究进展
引用本文:朱满康,段成辉,雷娜,刘立英,宋雪梅,侯育冬,严辉.Na_(1/2)Bi_(1/2)TiO_3基无铅压电体系退极化行为的研究进展[J].硅酸盐学报,2012,40(10):1403-1408.
作者姓名:朱满康  段成辉  雷娜  刘立英  宋雪梅  侯育冬  严辉
作者单位:1. 北京工业大学材料学院,北京,100124
2. 北京工业大学应用数理学院,北京,100124
基金项目:国家自然科学基金(51172006,51072008)
摘    要:简述了钛酸铋钠Na1/2Bi1/2TiO3,BNT]的相变过程及其退极化现象,介绍了退极化温度的确定方法,概述了NBT基复合体系准同型相界(MPB)附近的退极化行为,总结了有关退极化温度影响机制的几种观点。借鉴PbTiO3基高温压电体系的研究,提出采用具有小允差因子的Bi基钙钛矿Bi(B′B″)O3作为第二组元,与BNT形成新型无铅压电复合体系,以求提高MPB处的退极化温度,并简述了相关的研究报道。

关 键 词:钛酸铋钠  无铅压电  退极化  Bi基钙钛矿

Development of the Depolarization Behavior of Lead-Free Na1/2Bi1/2TiO3-Based Piezoelectrics
ZHU Mankang,DUAN Chenghui,LEI Na,SONG Xuemei,HOU Yudong,YAN Hui.Development of the Depolarization Behavior of Lead-Free Na1/2Bi1/2TiO3-Based Piezoelectrics[J].Journal of The Chinese Ceramic Society,2012,40(10):1403-1408.
Authors:ZHU Mankang  DUAN Chenghui  LEI Na  SONG Xuemei  HOU Yudong  YAN Hui
Affiliation:1.College of Materials Science and Engineering,Beijing University of Technology,Beijing 100124;2.College of Applied Science,Beijing University of Technology,Beijng 100124)
Abstract:The phase transition and depolarization phenomena of sodium bismuth titanate (Bi1/2Na1/2)TiO3,BNT] was reviewed.The methods determining the depolarization temperature were represented.Also,the depolarization behaviors of traditional BNT-based systems near morphotropic phase boundary(MPB) were summarized,and the mechanisms affecting the depolarization temperature of BNT-based systems were reviewed.A rule for the novel BNT-based complex systems was proposed via the introduction of Bi-based perovskite Bi(B′B″)O3as second end member.It was suggested that the BNT-Bi(B′B″)O3systems as-constituted could present a MPB at a high depolarization temperature by utilizing the feature of Bi(B′B″)O3with a low tolerance factor.
Keywords:sodium bismuth titanate  lead-free piezoelectrics  depolarization  Bi based perovskite
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