| 微波辐射条件下SAPO-5分子筛的合成与表征 |
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| 引用本文： | 杨 威,宋 宇,董 卉,徐同舟,黄城涛. 微波辐射条件下SAPO-5分子筛的合成与表征[J]. 大连工业大学学报, 2014, 0(2): 143-145 |
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| 作者姓名： | 杨 威 宋 宇 董 卉 徐同舟 黄城涛 |
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| 作者单位： | 大连工业大学纺织与材料工程学院; |
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| 基金项目： | 无机合成与制备化学国家重点实验室开放课题(2012-31);辽宁省教育厅A类项目(L201292) |
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| 摘 要： | 以异丙醇铝、磷酸、正硅酸乙酯为反应原料,三乙胺作为模版剂,功率800 W、180℃微波辐射30min合成了粒径均一、具有AFI拓扑结构的SAPO-5分子筛,系统研究了Al2O3与SiO2摩尔比和HF添加量等因素对产物长径比和晶体形貌的影响。采用XRD、SEM等分析手段对产物进行表征。结果表明,n(Al2O3)/n(SiO2)可以控制晶体尺寸的大小以及长径比,HF的存在影响晶体的成核及分散性。
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| 关 键 词： | SAPO-5分子筛 微波合成 表征 |
Synthesis and characterization of SAPO-5 molecular sieve by microwave irradiation |
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| Abstract: | SAPO-5 molecular sieve was compounded by microwave irradiation using Al(OPri)3, H3PO4,C8H20O4Si as the reaction material and triethylamine as a temple at 180℃for 30min.Some factors influencing on products such as n(Al2O3)/n(SiO2),HF dosage were systematically studied. The products were characterized by XRD,SEM and results showed that n(Al2O3)/n(SiO2)could control the crystal size and HF dosage could influence the nucleation and dispersion. |
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| Keywords: | SAPO-5 molecular sieve microwave synthesis characterization |
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