Edge‐Riched MoSe2/MoO2 Hybrid Electrocatalyst for Efficient Hydrogen Evolution Reaction |
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| Authors: | Chuanyong Jian Qian Cai Wenting Hong Jing Li Wei Liu |
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| Affiliation: | 1. CAS Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Provincial Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, P. R. China;2. University of Chinese Academy of Sciences, Beijing, P. R. China |
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| Abstract: | Molybdenum diselenide (MoSe2) is widely considered as one of the most promising catalysts for the hydrogen evolution reaction (HER). However, the absence of active sites and poor conductivity of MoSe2 severely restrict its HER performance. By introducing a layer of MoO2 on Mo foil, MoSe2/MoO2 hybrid nanosheets with an abundant edge and high electrical conductivity can be synthesized on the surface of Mo foil. Metallic MoO2 can improve the charge transport efficiency of MoSe2/MoO2, thereby enhancing the overall HER performance. MoSe2/MoO2 exhibits fast hydrogen evolution kinetics with a small overpotential of 142 mV versus RHE at a current density of 10 mA cm?2 and Tafel slope of 48.9 mV dec?1. |
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| Keywords: | hydrogen evolution reaction molybdenum dioxide molybdenum diselenide nanosheets |
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