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Biological removal of cyanide compounds from electroplating wastewater (EPWW) by sequencing batch reactor (SBR) system
Authors:Sirianuntapiboon Suntud  Chairattanawan Kanidta  Rarunroeng Methinee
Affiliation:Department of Environmental Technology, School of Energy Environment and Materials, King Mongkut's University of Technology Thonburi, Bangmod, Thung-kru, Bangkok 10140, Thailand. suntud.sir@kmutt.ac.th
Abstract:Biological treatment system especially, sequencing batch reactor (SBR) system could not be applied to treat the raw electroplating wastewater (EPWW) due to the low organic matter concentration of 10+/-3 mg-BOD5/L and toxic of high cyanide concentration of 23.0+/-2.2 mg-CN/L. However, EPWW could be used as the nitrogen source for the bio-sludge of SBR system. And 10% of EPWW (the final cyanide concentration of 2.3+/-0.2 mg/L) was most suitable to supplement into the wastewater as the nitrogen source. SBR system showed the highest COD, BOD5, TKN and cyanide removal efficiencies of 79+/-2%, 85+/-3%, 49.0+/-2.1% and 97.7+/-0.7%, respectively with 4-times diluted Thai-rice noodle wastewater (TRNWW) containing 10% EPWW and 138 mg/L NH4Cl (BOD5: TN of 100:10) at SRT of 72+/-13 days (under organic and cyanide loadings of 0.40 kg-BOD5/m3 d and 0.0023 kg-CN/m3 d, respectively). However, the effluent ammonia was still high of 22.6+/-0.4 mg-N/L while the effluent nitrate and nitrite was only 9.9+/-0.4 and 1.2+/-0.9 mg-N/L, respectively. And SVI and effluent SS of the system were higher than 95 and 75 mg/L, respectively.
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