| 含1,3,5-三嗪核结构的新型聚酰胺(PAMAM)树枝状化合物的合成 |
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| 引用本文： | 孟启,吴桂勇,李丹凤,陈娟娟,孙小强. 含1,3,5-三嗪核结构的新型聚酰胺(PAMAM)树枝状化合物的合成[J]. 化学试剂, 2011, 33(3): 215-218,223 |
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| 作者姓名： | 孟启 吴桂勇 李丹凤 陈娟娟 孙小强 |
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| 作者单位： | 江苏工业学院,江苏省精细石油化工重点实验室,江苏,常州,213164 |
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| 摘 要： | 以2,4,6,三氯-1,3,5-三嗪为核(GO)与亚胺基二乙酸二乙酯进行取代反应制得具有枝化的含有酯基官能团的树枝状化合物(G0.5),然后依次与乙二胺、丙烯酸甲酯和乙二胺反应分别制得含有1,3,5-三嗪核的G1.0、G1.5和G2.0代的树枝状化合物.采用FT-IR、1HNMR、13CNMR和ESI-MS对所合成的化...
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| 关 键 词： | 2,4,6-三氯-1,3,5-三嗪 1,3,5-三嗪 树枝状化合物 PAMAM |
Synthesis and characterization of poly(amidoamine) dendrimers with 1,3,5-triazine core |
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| MENG Qi,WU Gui-yong,LI Dan-fen,CHEN Juan-juan,SUN Xiao-qiang. Synthesis and characterization of poly(amidoamine) dendrimers with 1,3,5-triazine core[J]. Chemical Reagents, 2011, 33(3): 215-218,223 |
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| Authors: | MENG Qi WU Gui-yong LI Dan-fen CHEN Juan-juan SUN Xiao-qiang |
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| Affiliation: | MENG Qi,WU Gui-yong,LI Dan-feng,CHEN Juan-juan,SUN Xiao-qiang(Jiangsu Provincial Key Laboratory of Fine Petrochemical Engineering,Jiangsu Polytechnic University,Changzhou 213164,China) |
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| Abstract: | The polyamide dendron with a core of 1,3,5-triazine has been synthesized using 2,4,6-trichloro-1,3,5-triazine as the starting material by means of substitution reaction with diethyliminodiacetate to form the dendrimer with ester group(G0.5),followed by the amindation reaction and the Michael addition reaction with ethylenediamine and methyl acrylate to form G1.0,G1.5,and G2.0 dendrimers.The structures of target compounds were characterized by FT-IR,1HNMR and 13CNMR.The fluorescent emission spectrogram of G2... |
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| Keywords: | PAMAM |
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