| 超声波条件下水杨醛的简便合成 |
| |
| 引用本文： | 王均雷,陈海群. 超声波条件下水杨醛的简便合成[J]. 化学试剂, 2011, 33(2): 182-184 |
| |
| 作者姓名： | 王均雷 陈海群 |
| |
| 作者单位： | 江苏工业学院,化学化工学院,江苏,常州,213164 |
| |
| 摘 要： | 探索了在超声波辐射下,以苯酚、多聚甲醛、无水氯化镁和三乙胺为原料合成标题化合物的工艺路线.重点考察了原料配比、温度及加热方式、溶剂种类对反应收率的影响.确定了最佳反应条件为:n(苯酚):n(多聚甲醛):n(无水氯化镁):n(三乙胺)=1:3:1.5:1.5;四氢呋喃为溶剂;采用逐步加热方式;反应时间3 h.在该条件下水...
|
| 关 键 词： | 超声波 苯酚 甲酰化 水杨醛 |
Facile synthesis of salicylaldehyde under ultrasonic irradiation |
| |
| WANG Jun-lei,CHEN Hai-qun. Facile synthesis of salicylaldehyde under ultrasonic irradiation[J]. Chemical Reagents, 2011, 33(2): 182-184 |
| |
| Authors: | WANG Jun-lei CHEN Hai-qun |
| |
| Affiliation: | WANG Jun-lei,CHEN Hai-qun* (School of Chemistry and Chemical Engineering,Jiangsu Polytechnic University,Changzhou 213164,China) |
| |
| Abstract: | Investigation has been made on the process for synthesis of salicylaldehyde using phenol,anhydrous magnesium chloride,triethylamine and paraformaldehyde as starting materials.Improvements were made as follows.According to the characteristics of the reaction,the process was divided into two steps.Firstly,magnesium phenoxide was prepared from phenol and magnesium dichloride.Then paraformaldehyde was added.The results showed that the optimal conditions were as follows:The molar ratio of phenol,paraformaldehyde... |
| |
| Keywords: | ultrasonic phenol formylation salicylaldehyde |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
|
