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Microstructures and thermal properties of municipal solid waste incineration fly ash
Authors:Yuan-yuan Liu  Jia-jia Wang  Xiang Lin  Li-ao Wang  Shan Zhong and Wei Yang
Affiliation:[1]Key Laboratory of The Three Gorges Reservoir Region's Eco-environmental of Ministry of Education, Chongqing University, Chongqing 400044, China [2]College of Resources and Environmental Science, Chongqing University, Chongqing 400044, China [3]College of Environment and Resources, Guangxi Normal University, Guilin 541004, China
Abstract:To analyze the feasibility of utilization of thermal technology in fly ash treatment, thermal properties and microstructures of municipal solid waste incineration (MSWI) fly ash were studied by measuring the chemical element composition, specific surface area, pore sizes, functional groups, TEM image, mineralogy and DSC-TG curves of raw and sintered fly ash specimens. The results show that MSWI fly ash particles mostly have irregular shapes and non-typical pore structure, and the supersonic treatment improves the pore structure; MSWI fly ash consists of such crystals as SiO2, CaSO4 and silica-aluminates, and some soluble salts like KCl and NaCl. During the sintering process, mineralogy changes largely and novel solid solutions are produced gradually with the rise of temperature. Therefore, the utilization of a proper thermal technology not only destructs those persistent organic toxicants but also stabilizes hazardous heavy metals in MSWI fly ash.
Keywords:municipal solid waste incineration  fly ash  thermal treatment  sintering  microstructure
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