Easy one-pot method to control the morphology of polyethylene/carbon nanotube nanocomposites using metallocene catalysts |
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Authors: | Bijal Kottukkal Bahuleyan Muataz Ali Atieh Sadhan Kumar De Masihullah Jabarulla Khan and Mamdouh A Al-Harthi |
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Affiliation: | (1) Department of Chemical Engineering, King Fahd University of Petroleum and Minerals, 31261 Dhahran, Saudi Arabia;(2) Center of Research Excellence in Nanotechnology, King Fahd University of Petroleum and Minerals, 31261 Dhahran, Saudi Arabia; |
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Abstract: | An easy one pot method is demonstrated for the controlled periodical surface coating of polyethylene over multiwalled carbon
nanotubes (MWCNT) by insitu polymerization of ethylene using highly active metallocene catalysts (Cp2ZrCl2 and Cp2TiCl2) in combination with methylalumoxane. The crystallinity of the nanocomposite was increased and its morphology could be tuned
from “sausage” like to “shish-kebab” in the presence of CNT depending on the experimental condition and choice of metal atom. |
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