| 三氯氧磷法合成辛基酚聚氧乙烯醚磷酸酯 |
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| 引用本文： | 荣新明,刘晓玲,王静,仉莉,葛际江,张贵才.三氯氧磷法合成辛基酚聚氧乙烯醚磷酸酯[J].精细石油化工,2010,27(1). |
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| 作者姓名： | 荣新明 刘晓玲 王静 仉莉 葛际江 张贵才 |
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| 作者单位： | 中国石油大学(华东)石油工程学院采油化学研究室,山东,青岛,266555 |
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| 基金项目： | 霍英东教育基金会第十一届高等院校青年教师基金(优选资助课题)资助项目 |
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| 摘 要： | 实验以三氯氧磷为磷酸化试剂合成了辛基酚聚氧乙烯醚磷酸酯,最佳合成条件为:n(POCl_3):n(OP-4)=1.2:1,酯化温度40～50℃,水解量10%,水解温度60℃,水解时间3～4 h。产物均为单双酯混合物,其中单酯质量分数大于87%,双酯质量分数约3%,酯化率大于90%。
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| 关 键 词： | 辛基酚聚氧乙烯醚磷酸酯 辛基酚聚氧乙烯醚 三氯氧磷 磷酸酯化 合成 |
SYNTHESIS OF OCTYL-PHENOL-POLYOXYTHYLENE ETHER PHOSPHATE |
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| Rong Xinming,Liu Xiaoling,Wang Jing,Zhang Li,Ge Jijiang,Zhang Guicai.SYNTHESIS OF OCTYL-PHENOL-POLYOXYTHYLENE ETHER PHOSPHATE[J].Speciality Petrochemicals,2010,27(1). |
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| Authors: | Rong Xinming Liu Xiaoling Wang Jing Zhang Li Ge Jijiang Zhang Guicai |
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| Abstract: | Octylphenol polyoxyethylene ether phosphate(OPP) was synthesized by phosphorylation using phosphorus oxychloride.The effects of six influencing factors on the yield of monoester,diester and esterification,such as the molar ratio,esterification temperature and time,the volume of hydrolysis and hydrolysis temperature and time,were investigated.The optimal reaction conditions for OPP were found as follows:molar ratio of POCl_3 to OP-4 1.2,esterification temperature 40 - 50℃,hydrolysis fraction 10%,hydrolysis temperature 60℃and hydrolysis time 3 - 4 h.The synthesized products were all the mixtures of monoester and Diester,of which the highest level of monoester could reach above 87%,with the content of diester about 3%and the yield of esterification more than 90%. |
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| Keywords: | octylphenol polyoxyethylene ether phosphate octyphenol polyoxyethylene ether phosphorus oxychloride phosphoric esterification synthesis |
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