| 负载型固体碱催化合成三氟碘甲烷 |
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| 引用本文： | 马洋博,吕剑,张伟,王博.负载型固体碱催化合成三氟碘甲烷[J].化学试剂,2010,32(3). |
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| 作者姓名： | 马洋博 吕剑 张伟 王博 |
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| 作者单位： | 西安近代化学研究所,七部,陕西,西安,710065 |
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| 摘 要： | 将碱金属、碱土金属盐负载在活性炭载体上制备的多种负载型固体碱作为催化剂,应用于五氟乙烷、氧气和碘合成标题化合物的实验表明,所制备的固体碱中钾盐催化活性高,选择性好,是理想的活性组分。
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| 关 键 词： | 固体碱 碱金属盐 活性炭 |
Supported solid base-catalyzed synthesis of trifluoroiodo-methane |
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| MA Yang-bo,LV Jian,ZHANG Wei,WANG Bo.Supported solid base-catalyzed synthesis of trifluoroiodo-methane[J].Chemical Reagents,2010,32(3). |
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| Authors: | MA Yang-bo LV Jian ZHANG Wei WANG Bo |
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| Abstract: | Supported solid bases were prepared by loading alkali metal salts and alkaline earth metal salts on activated carbon,and were used as catalysts for synthesis of trifluoroiodomethane from C_2F_5H,O_2 and iodine.The results showed that K salt was the optimum catalyst for this reaction. |
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| Keywords: | CF_3I solid base CF_3I alkali metal salts activated carbon |
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