Reforming of methane with carbon dioxide over supported bimetallic catalysts containing Ni and noble metal: I. Characterization and activity of SiO2 supported Ni–Rh catalysts |
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Authors: | WK J
wiak M Nowosielska J Rynkowski |
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Affiliation: | Institute of General and Ecological Chemistry, Technical University of Lodz, ul. Zeromskiego 116, 90-924 Lodz, Poland |
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Abstract: | Cobalt catalysts supported on silica aerogel have been prepared using sol–gel chemistry followed by drying under supercritical ethanol conditions. Three different loadings of cobalt were synthesized: 2, 6, and 10% by weight. Transmission electron micrographs indicate that the metallic cobalt exists as discrete particles 50–70 nm in diameter for the 2 and 6% loadings. The 10% catalyst shows long needles of cobalt. BET and BJH measurements indicate that the catalysts retain the silica aerogel properties of high surface area (∼800 m2/g), large pore volume (∼5 cm3/g), and an average pore diameter in the mesoporous regime (∼25 nm). The catalysts were evaluated for Fischer–Tropsch activity in a laboratory-scale packed bed reactor. All three catalysts were active with the 10% Co catalyst achieving more than 20% CO conversion which corresponds to a rate of 1.53 g CO per g-cat per hour. The catalysts were selective for the C10+ hydrocarbons with more than 50% of the carbon contained within this fraction. A significant portion of the C9–C15 hydrocarbon product was observed as 1-olefins which reflects the enhanced mass transport within the very porous aerogel support. |
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Keywords: | Dry reforming of methane Ni–Rh SiO2 TP techniques XRD FT-IR Carbon deposit |
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