| 过渡金属氮化物催化性能研究进展 |
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| 引用本文： | 张新波,张雅娟.过渡金属氮化物催化性能研究进展[J].工业催化,2011,19(1):11-15. |
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| 作者姓名： | 张新波 张雅娟 |
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| 作者单位： | 1.浙江医药高等专科学校，浙江 宁波 315100;;2.浙江工业大学工业催化研究所，绿色化学合成技术国家重点实验室培育基地，浙江 杭州 310032 |
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| 摘 要： | 过渡金属氮化物具有类似于Pt族贵金属的催化性能得到了广泛的研究.综述了过渡金属氮化钼及助剂促进的氮化钼在加氢脱硫与脱氮、氨合成与分解、芳烃加氢和其他涉氢反应(如炔烃、烯烃加氢、丙酮缩合、肼的分解)中的应用,并介绍了其他金属氮化物(如氮化钒、氮化钴)在催化反应中的应用.
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| 关 键 词： | 催化化学 过渡金属氮化物 加氢脱硫 加氢脱氮 芳烃加氢 |
Research progress in catalytic properties of transition metal nitrides |
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| ZHANG Xinbo,ZHANG Yajuan.Research progress in catalytic properties of transition metal nitrides[J].Industrial Catalysis,2011,19(1):11-15. |
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| Authors: | ZHANG Xinbo ZHANG Yajuan |
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| Affiliation: | 1.Zhejiang Pharmaceutical College,Ningbo 315000,Zhejiang,China; ;2.Institute of Industrial Catalysis,State Key Laboratory Breeding Base of Green Chemistry Synthesis Technology,Zhejiang University of Technology,Hangzhou 310012,Zhejiang,China |
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| Abstract: | Transition metal nitrides are known as platinum-like metal on catalytic reaction. The application of molybdenum nitrides and mol and have been studied extensively ybdenum nitrides promoted by the assistants in hydrodesulfurization and hydrodenitrogenation, ammonia synthesis and decomposition, and aromatic hydrogenation and other hydrogen-involving reactions （such as the hydrogenation of alkynes and alkenes, acetone condensation, hydrazine decomposition） was reviewed. The application of other metal nitrides（ such as vanadium nitrides and cobalt nitrides） in catalytic reactions was introduced. |
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| Keywords: | catalytic chemistry transition metal nitride hydrodesulfurization hydrodenitrogenation aromatic hydrogenation |
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