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An a-Si:H vacuum-compatible photoresist process for fabricating device structures in HgCdTe
Authors:R. E. Hollingsworth  C. Dehart  Li Wang  J. N. Johnson  J. D. Benson  J. H. Dinan
Affiliation:(1) Materials Research Group, Inc., 12441 W. 49th Ave., 80033 Wheat Ridge, CO;(2) E-OIR Measurements, Inc., 9241 Courthouse Rd., 22553 Spotsylvania, VA;(3) U.S. Army CECOM Night Vision & Electronic Sensors Directorate, 10221 Burbeck Road, 22060 Fort Belvoir, VA
Abstract:A process for transferring patterns into HgCdTe epilayers using a hydrogenated amorphous silicon (a-Si:H) photomask has been demonstrated. a-Si:H films were grown using plasma enhanced chemical vapor deposition (PECVD). A latent image of a projected mask pattern was created at the a-Si:H surface by ultraviolet enhanced oxidation in the load lock of the PECVD vacuum chamber. This image was transformed into a mask by hydrogen plasma removal of the unexposed areas. A hydrogen plasma etch selectivity value greater than 500:1 for oxide and a-Si:H allows patterns as thick as 700 nm to be generated. a-Si:H masks were used to create arrays of mesas in planar HgCdTe epilayers by etching in an electron cyclotron resonance (ECR) plasma reactor. Etch selectivity between a-Si:H and HgCdTe during an ECR hydrogen plasma etch was measured to be greater than 18:1. RoA values > 103 were obtained for mid-wavelength infrared diodes made from HgCdTe heterojunctions using a-Si:H masks.
Keywords:Dry processing  HgCdTe  pattern transfer
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