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炼油厂含油污泥与高硫石油焦的共成浆性
引用本文:吴颜,张强,李伟锋,刘海峰.炼油厂含油污泥与高硫石油焦的共成浆性[J].石油学报(石油加工),2012,28(1):155-160.
作者姓名:吴颜  张强  李伟锋  刘海峰
作者单位:华东理工大学 煤气化教育部重点实验室, 上海 200237
基金项目:国家自然科学基金,中国石油科技创新基金
摘    要:利用炼油厂产生的含油污泥和高硫石油焦,采用萘系分散剂制成油泥焦浆。分别考察了含油污泥处理前后与石油焦的成浆性能。结果表明,未经处理的含油污泥可与石油焦共成浆,但成浆浓度远低于石油焦浆;加入硫酸铁后油泥焦浆表观黏度和流动性得到改善,成浆浓度提高;电解质对浆体的降黏效果优于表面活性剂。含油污泥的加入改变了石油焦浆体的流变类型,随着剪切速率增大,油泥焦浆的表观黏度降低,属于假塑性流体;含油污泥的加入提高了石油焦浆体的稳定性,起到了稳定剂的作用。

关 键 词:含油污泥  高硫石油焦  油泥焦浆  硫酸铁  成浆性  
收稿时间:2010-12-08

Co-Slurry Ability of Refinery Oil Sludge and High Sulphur Petroleum Coke
WU Yan , ZHANG Qiang , LI Weifeng , LIU Haifeng.Co-Slurry Ability of Refinery Oil Sludge and High Sulphur Petroleum Coke[J].Acta Petrolei Sinica (Petroleum Processing Section),2012,28(1):155-160.
Authors:WU Yan  ZHANG Qiang  LI Weifeng  LIU Haifeng
Affiliation:Key Laboratory of Coal Gasification of Education Ministry of China, East China University of Scicence and Technology, Shanghai 200237, China
Abstract:The co-slurry ability of the refinery oil sludge and high sulfur petroleum coke and with naphthalene condensate as dispersant was investigated,including concentration,rheology and stabilization.Results showed that oil sludge could mix with petroleum coke to make slurry,but the slurry concentration was lower than that of the single petroleum coke slurry.The apparent viscosity of oil sludge-petroleum coke-slurry was reduced and its flow ability was improved both by the addition of ferric sulfate,at the same time,the slurry concentration was increased.The electrolyte ferric sulfate could reduce the apparent viscosity of oil sludge-petroleum coke-slurry more than surfactant.The addition of oily sludge into the petroleum coke slurry changed slurry rheological type,and as increase of shearing rate,the apparent viscosity of oil sludge-petroleum coke-slurry decreased,so oil sludge-petroleum coke-slurry belonged to pseudoplastic fluid.Oil sludge played the role of stabilizer in oil sludge-petroleum coke-slurry and the more addition of oil sludge,the better stabilization of petroleum coke-slurry.
Keywords:oil sludge  high sulfur petroleum coke  oil sludge-petroleum coke-slurry  ferric sulfate  slurry ability
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