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聚丙烯酸酯/纳米碳酸钙复合增韧PVC的研究
引用本文:马治军,杨景辉,吴秋芳.聚丙烯酸酯/纳米碳酸钙复合增韧PVC的研究[J].塑料工业,2011,39(3).
作者姓名:马治军  杨景辉  吴秋芳
作者单位:华东理工大学,国家超细粉末工程研究中心,上海,200231
摘    要:制备了复合增韧改性剂聚丙烯酸酯/纳米CaCO3(PA-C),并将其用于硬质聚氯乙烯(PVC)中,以研究其增韧效果.使用扫描电子显微镜(SEM)观察了复合材料的微观结构,并测试了复合材料的力学性能.结果表明:PA-C均匀分散于PVC基体中;当在PVC中添加10份PA-C时,复合材料的缺口冲击强度达到88.2kJ/m2,冲击强度和弯曲模量明显增大,拉伸强度未明显降低;SEM照片显示PA-C有效地引发了PVC基体产生塑性形变,有利于能量的吸收.

关 键 词:纳米碳酸钙  聚丙烯酸酯  增韧  聚氯乙烯  拉伸强度  冲击性能

Study on Polyacrylate/Nano-CaCO3 Composite Toughened PVC
MA Zhi-jun,YANG Jing-hui,WU Qiu-fang.Study on Polyacrylate/Nano-CaCO3 Composite Toughened PVC[J].China Plastics Industry,2011,39(3).
Authors:MA Zhi-jun  YANG Jing-hui  WU Qiu-fang
Affiliation:MA Zhi-jun,YANG Jing-hui,WU Qiu-fang(East China University of Science and Technology,National Engineering Research Center of Ultrafine Powder,Shanghai 200231,China)
Abstract:The polyacrylate/nano-CaCO3(PA-C)composite toughening hard PVC was successfully prepared and the toughening effect was researched.The effects of polyacrylate/nano-CaCO3 composite on the mechanical properties and micro-morphology of PVC were investigated by SEM.It was found that PA-C dispersed in PVC matrix uniformly.The addition of PA-C 10 phr in PVC could make the notched impact strength of composite reach to 88.2 kJ/m2,the impact strength and the flexure modulus increased obviously,led to a slight decreas...
Keywords:Polyacrylate  Nano-CaCO3  Toughing  PVC  Tensile Strength  Impact Strength  
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