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胶粉氯化及改性PVC
引用本文:赵永仙,王吉辉,姚薇,黄宝琛. 胶粉氯化及改性PVC[J]. 弹性体, 2009, 19(1): 53-56
作者姓名:赵永仙  王吉辉  姚薇  黄宝琛
作者单位:青岛科技大学橡塑材料与工程教育部重点实验室,山东青岛,266042
基金项目:青岛绿叶科技有限责任公司合作项目 
摘    要:通过水相悬浮法制备了氯化胶粉,并用氯化胶粉对聚氯乙烯(PVC)进行了改性。结果表明:提高反应温度和延长反应时间都可使胶粉氯含量增加;随氯化胶粉用量的增加,改性PVC的拉伸强度、弯曲强度下降,但其断裂伸长率提高;综合氯化胶粉的氯含量对PVC各项力学性能的影响程度,取氯质量分数为20%~40%时可对PVC起到较好的增韧效果,同时断裂伸长率增加。

关 键 词:胶粉  氯化胶粉  改性  聚氯乙烯

Chlorination of rubber powder and modification of PVC by chloride rubber powder
ZHAO Yong-xian,WANG Ji-hui,YAO Wei,HUANG Bao-chen. Chlorination of rubber powder and modification of PVC by chloride rubber powder[J]. China Elastomerics, 2009, 19(1): 53-56
Authors:ZHAO Yong-xian  WANG Ji-hui  YAO Wei  HUANG Bao-chen
Affiliation:( Key Laboratory of Rubber-Plastics of Education Ministry, Qingdao University of Science and Technology, Qingdao 266042, China)
Abstract:Chloride rubber powder was prepared by water phase suspension method,and used to modify the PVC. The results showed that,with the increasing of reaction temperature and prolonging reaction time, chlorine content increased. As the chloride rubber powder degree increased, the tensile strength and bending strength of modified PVC reduced but the breaking elongation increased. According to the effect of chloride content of chloride rubber powder on the mechanical properties of PVC, good effect of toughening could be gotten and the elongation increased when the chlorine content ranged from twenty percent to forty percent.
Keywords:rubber powder  chloride rubber powder  modification  polyvinyl chloride(PVC)
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