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Synthesis of Block Copolymers containing Chain‐Controlled Aramid and Fluoroethylene Segments
Authors:Arata Korematsu  Tsutomu Furuzono  Akio Kishida
Abstract:Summary: Novel block copolymers containing aromatic polyamide (aramid) and fluoroethylene segments were synthesized by a two‐step solution polycondensation. This synthetic method could control the chain‐length of aramid segments and these copolymers could have high structural regularity. The number‐average molecular weight (equation image ) of one of these polymers is over 2.0 × 104. Incorporating fluoroethylene segments improves the solubility of the resulting polymer compared with conventional aramids.
image

The synthesis of the fluoroethylene‐aramid block copolymers.

Keywords:aramid  block copolymers  chain‐control  fluoroethylene  polycondensation
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