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原子层沉积方法制备低温多层Al2O3/TiO2复合封装薄膜的研究
引用本文:周忠伟,李民,徐苗,邹建华,王磊,彭俊彪.原子层沉积方法制备低温多层Al2O3/TiO2复合封装薄膜的研究[J].液晶与显示,2016,31(6):532-539.
作者姓名:周忠伟  李民  徐苗  邹建华  王磊  彭俊彪
作者单位:1. 华南理工大学 材料科学与工程学院, 广东 广州 510641;
2. 创维液晶器件(深圳)有限公司, 广东 深圳 518108
基金项目:深圳市技术攻关计划(No.JSGG20150331171053333);广州市平板显示行业工程技术研究中心资助项目(No.2060502)
摘    要:原子层沉积(ALD)方法可以制备出高质量薄膜,被认为是可应用于柔性有机电致发光器件(OLED)最有发展前景的薄膜封装技术之一。本文采用原子层沉积(ALD)技术,在低温(80℃)下,研究了Al2O3及TiO2薄膜的生长规律,通过钙膜水汽透过率(WVTR)、薄膜接触角测试等手段,研究了不同堆叠结构的多层Al2O3/TiO2复合封装薄膜的水汽阻隔特性,其中5 nm/5 nm×8 dyads(重复堆叠次数)的Al2O3/TiO2叠层结构薄膜的WVTR达到2.1×10-5 g/m2/day。采用优化后的Al2O3/TiO2叠层结构薄膜对OLED器件进行封装,实验发现封装后的OLED器件在高温高湿条件下展现了较好的寿命特性。

关 键 词:有机电致发光器件  薄膜封装  原子层沉积  水汽透过率
收稿时间:2016-01-12

Low-temperature multi-layer Al2O3/TiO2 composite encapsulation thin film by atomic layer deposition
ZHOU Zhong-wei,LI Min,XU Miao,ZOU Jian-hua,WANG Lei,PENG Jun-biao.Low-temperature multi-layer Al2O3/TiO2 composite encapsulation thin film by atomic layer deposition[J].Chinese Journal of Liquid Crystals and Displays,2016,31(6):532-539.
Authors:ZHOU Zhong-wei  LI Min  XU Miao  ZOU Jian-hua  WANG Lei  PENG Jun-biao
Affiliation:1. School of Materials Science and Engineering, South China University of Technology, Guangzhou 510641, China;
2. Skyworth LCD Co. Ltd, Shenzhen 518108, China
Abstract:Atomic layer deposition (ALD) is considered as one of the most promising thin-film encapsulation technologies for flexible organic light-emitting diode (OLED) device because of high-quality films formed. In this work, different laminated structures of Al2O3/TiO2 composite film were prepared at low temperature (80℃) by ALD method. The growth mechanism of Al2O3 and TiO2 film was studied. The water vapor barrier properties of the different stacked structures of composite Al2O3/TiO2 thin film were studied by the calcium film, which were analyzed by water vapor transmission rate (WVTR) test and contact angle measurements. The WVTR of the 5 nm/5 nm×8 dyads Al2O3/TiO2 composite thin film was 2.1×10-5 g/m2/day and the OLED devices encapsulated by this optimized Al2O3/TiO2 structure exhibited better lifetime characteristics in high temperature and high humidity test.
Keywords:organic electroluminescent devices  thin film encapsulation  atomic layer deposition  water vapor transmission rate
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