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Fracture toughness and impact strength of anhydride‐cured biobased epoxy
Authors:Hiroaki Miyagawa  Manjusri Misra  Lawrence T Drzal  Amar K Mohanty
Abstract:Biobased neat epoxy materials containing functionalized vegetable oils (FVO), such as epoxidized linseed oil (ELO) and epoxidized soybean oil (ESO), were processed with an anhydride curing agent. A percentage of diglycidyl ether of bisphenol F (DGEBF) was replaced by ELO or ESO. The selection of the DGEBF, FVO, and an anhydride‐curing agent resulted in an excellent combination to produce a new biobased epoxy material having a high elastic modulus and high glass transition temperature. Izod impact strength and fracture toughness were significantly improved dependent on FVO content, which produced a phase‐separated morphology. POLYM. ENG. SCI., 45:487–495, 2005. © 2005 Society of Plastics Engineers
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