| 孔道层状己二酸多聚体的制备及晶体结构 |
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| 引用本文： | 赵卫星. 孔道层状己二酸多聚体的制备及晶体结构[J]. 化工时刊, 2013, 0(9): 13-14,32 |
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| 作者姓名： | 赵卫星 |
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| 作者单位： | 宝鸡文理学院化学化工学院,陕西宝鸡721013 |
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| 基金项目： | 宝鸡文理学院重点项目（ZKl2016） |
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| 摘 要： | 采用水热法,以己二酸和水为原料,在碱性条件下,制备了一种新型的具有孔道二维层状己二酸多聚体。利用X-射线单晶衍射对其结构进行了测定,结果表明:该晶体属于单斜晶系,P1 21/c空间群,a=7.195(4),b=5.150(3),c=10.022(6),α=90.00°,β=111.019(9)°,γ=90.00°,V=346.65(30)3,Z=2,Dc=1.40002 g·cm3,F(000)=156,R gt(F)=0.0371,w R ref(F2)=0.0908。
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| 关 键 词： | 水热法 己二酸 晶体结构 孔道 |
Preparation and Crystal Structure of Adipic Acid Polymer with Pore Layer |
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| Zhao Weixing. Preparation and Crystal Structure of Adipic Acid Polymer with Pore Layer[J]. Chemical Industry Times, 2013, 0(9): 13-14,32 |
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| Authors: | Zhao Weixing |
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| Affiliation: | Zhao Weixing (College of Chemistry and Chemical Engineering, Baoji University of Arts and Sciences ,Shaanxi ,Baoji 721013 ) |
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| Abstract: | The novel pore 2D layered poly was prepared with adipie acid and water as raw materials and alkaline conditions by hydrothermal synthesis reaction. By single crystal X - ray diffraction of its structure determined, the re- suits showed that： The crystal belongs to monoclinic space group P1 21/c,a=7.95（4）А,b=5.150（3）А,c=10.022（6）А,α=90.00.00°,β=111.019（9）°,γ=90.00°,V=346.65（30）А^3,Z=2,Dc=1.40002g·cm^3,r（000）=156,Rgt（F）=0.0371,wRref（F^2）=0.0908. |
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| Keywords: | Hydrothermal synthesis Adipic acid Crystal structure Pore |
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