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CTLA陶瓷微波介电性能及烧结特性研究
引用本文:方有维,刘林,庄文东,唐斌,张树人.CTLA陶瓷微波介电性能及烧结特性研究[J].压电与声光,2012,34(2):288-292.
作者姓名:方有维  刘林  庄文东  唐斌  张树人
作者单位:1. 电子科技大学电子薄膜与集成器件国家重点实验室,四川成都,610054
2. 成都泰格微波技术股份有限公司,四川成都,611731
基金项目:国家国际科技合作基金资助项目(0102010DFB13800)
摘    要:采用固相反应法制备了0.65CaTiO3-0.35LaAlO3(CTLA)陶瓷,研究了CTLA陶瓷的物相组成、烧结特性及微波介电特性。结果表明,CTLA陶瓷只含有Ca0.65La0.35Al0.35Ti0.65O3主晶相,不存在第二相。烧结温度在1 380~1 450℃间,陶瓷的微波介电性能最佳,介电常数εr=44.5,频率温度系数τf≈0,品质因数与频率之积Q×f≈43 948GHz。当w(Nb2O5)=10%时能使陶瓷致密化烧结温度降到1 300℃,但微波性能变差,εr=38.3,τf=-2.8×10-6/℃,Q×f=13 260GHz。

关 键 词:微波介质陶瓷  Ca0.65La0.35Al0.35Ti0.65O3  介电常数  品质因数  频率温度系数

Study on the Microwave Dielectric and Sintering Properties of CTLA Ceramics
FANG Youwei,LIU Lin,ZHUANG Wendong,TANG Bin and ZHANG Shuren.Study on the Microwave Dielectric and Sintering Properties of CTLA Ceramics[J].Piezoelectrics & Acoustooptics,2012,34(2):288-292.
Authors:FANG Youwei  LIU Lin  ZHUANG Wendong  TANG Bin and ZHANG Shuren
Affiliation:1(1.State Key Lab.of Electronic Thin Films and Integrated Devices,University of Electronic Science and Technology of China, Chengdu 610054,China;2.Chengdu Tiger Microwave Technology Co.,Ltd.,Chengdu 611731,China)
Abstract:The microwave dielectric ceramics 0.65CaTiO3-0.35LaAlO3(CTLA) was prepared by solid state reaction technique.The crystal structure,sintering properties and microwave dielectric properties of the CTLA ceramics were investigated.The results showed that the CTLA ceramics only had the main phase of Ca0.65La0.35Al0.35Ti0.65O3 without a second phase.The CTLA ceramics sintered between 1 380~1 450 ℃ exhibited excellent microwave dielectric properties:εr=44.5,τf≈0,Q×f≈43 948 GHz.The additives of 10% Nb2O5 increased densification sintering temperature to 1 300 ℃ but microwave properties was variant.εr=38,τf=-2.8×10-6/°C and Q×f=13 260 GHz.
Keywords:microwave dielectric ceramics  Ca0  65La0  35Al0  35Ti0  65O3  dielectric constant  quality factor  frequency-temperature coefficient
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