| 高等规聚3-己基噻吩的合成与研究 |
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| 引用本文： | 宋长伟,汪瑾,程发祥,周正发.高等规聚3-己基噻吩的合成与研究[J].广州化工,2010,38(12):12-14,17. |
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| 作者姓名： | 宋长伟 汪瑾 程发祥 周正发 |
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| 作者单位： | 合肥工业大学化工学院,安徽合肥230009 |
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| 摘 要： | 基于GRIM法合成了高等规的聚3-己基噻吩(rr-P3HT),研究了反应中催化剂和格氏试剂用量、反应温度和时间对产物产率的影响。采用GPC、1H-NMR和TGA法对其结构进行表征,结果显示该聚合物具有高度的规整性和良好的热稳定性。通过紫外吸收光谱、荧光发射光谱表征了聚合物的光物理性能,其最大紫外吸收峰和相应的发射峰分别位于455nm和573nm。
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| 关 键 词： | 聚3-己基噻吩 等规 紫外 热稳定性 |
Synthesis and Characterization of Poly(3-hexylthiophene) with Highly Regularity |
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| SONG Chang-wei,WANG Jin,CHENG Fa-xiang,ZHOU Zheng-fa.Synthesis and Characterization of Poly(3-hexylthiophene) with Highly Regularity[J].GuangZhou Chemical Industry and Technology,2010,38(12):12-14,17. |
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| Authors: | SONG Chang-wei WANG Jin CHENG Fa-xiang ZHOU Zheng-fa |
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| Affiliation: | (School of Chemical Engineering,Hefei University of Technology,Anhui Hefei 230009,China) |
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| Abstract: | Highly regularity poly（3-hexylthiophene）（rr-P3HT） was synthesized based on the GRIM method.The influences of reaction temperature,reaction time,and the amounts of catalyst and Grignard reagent on the yields were investigated.The chemical structure of rr-P3HT was characterized by means of GPC,^1H-NMR and TGA.The results showed that rr-P3HT exhibited with highly regularity and good thermal stability.The photophysical properties of rr-P3HT were investigated by ultraviolet-visible absorption spectrum and fluorescence emission spectrum.The maximum UV-vis wavelength and corresponding emitting wavelength were 455nm and 573nm,respectively. |
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| Keywords: | poly（3-hexylthiophene） regularity ultraviolet fluorescence |
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