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Sn40Pb共晶合金电镀工艺
引用本文:甘英杨,刘玉,甘贵生,吴懿平.Sn40Pb共晶合金电镀工艺[J].精密成形工程,2017,9(1):109-113.
作者姓名:甘英杨  刘玉  甘贵生  吴懿平
作者单位:华中科技大学,武汉 430074,重庆理工大学,重庆 401320,重庆理工大学,重庆 401320,华中科技大学,武汉 430074
摘    要:目的对Sn40Pb共晶合金电镀工艺过程进行研究。方法采用电镀和超声辅助搅拌,Sn40Pb作为电镀阳极,在铜片上成功的制备了Sn40Pb共晶合金镀层。结果研究表明随着电流密度增大,镀层厚度增加,镀层中铅含量增加较快,电流密度过大时阴极析氢反应剧烈,锡铅镀层会变得粗糙,致密性变差。结论当电镀液成分为甲基磺酸为12 m L(24 g/L)、甲基磺酸锡为8 m L(16 g/L)、甲基磺酸铅为3.7 m L时,控制电流密度在4 A/dm~2、电镀时间为5 min左右,可以获得接近锡铅共晶的理想合金镀层。

关 键 词:电镀  锡铅合金  电流密度  镀液配方  Pb2+浓度  形貌
收稿时间:2016/11/21 0:00:00
修稿时间:2017/1/10 0:00:00

Electroplating Process of Sn40Pb Eutectic Alloy
GAN Ying-yang,LIU Yu,GAN Gui-sheng and WU Yi-ping.Electroplating Process of Sn40Pb Eutectic Alloy[J].Journal of Netshape Forming Engineering,2017,9(1):109-113.
Authors:GAN Ying-yang  LIU Yu  GAN Gui-sheng and WU Yi-ping
Affiliation:Huangzhong University of Science and Technology, Wuhan 430074, China,Chongqing University of Technology, Chongqing 401320, China,Chongqing University of Technology, Chongqing 401320, China and Huangzhong University of Science and Technology, Wuhan 430074, China
Abstract:The paper aims to study the electroplating process of Sn40Pb eutectic alloy. Sn40Pb was used as the electroplating anode. Sn40Pb eutectic alloy coating was prepared on the copper successfully by electroplating and stirring assisted with eultrasonic. The lead content in the coating increased rapidly with the increase of current density and coating thickness. When the current density was too large, the hydrogen evolution reaction at the cathoad was violent, the Sn-Pb Alloy Coating was roughened, and compactness was worsened. When the plating solution composition for methyl sulfonic acid is 12 mL (24 g/L), methyl sulfonic acid tin is 8 mL (16 g/L), and methyl sulfonic acid lead is 3.7 mL, ideal alloy coating which is close to Sn Pb eutectic can be obtained under the condition that the current density is 4 A/dm2 and the electroplating time is about 5 min.
Keywords:electroplating  Sn-Pb alloy  current density  plating solution composition  the density of Pb2+  morphology
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