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Kinetics of Sawdust Hydrolysis with Dilute Hydrochloric Acid and Ferrous Chloride
Authors:YUAN Chuan-min  YAN Yong-jie  REN Zheng-wei  LI Ting-chen  CAO Jian-qin
Affiliation:Dept.Chem.Technol.Energy Resources, East China Univ.Sci.& Technol., Shanghai 200237, China;Dept.Chem.Technol.Energy Resources, East China Univ.Sci.& Technol., Shanghai 200237, China;Dept.Chem.Technol.Energy Resources, East China Univ.Sci.& Technol., Shanghai 200237, China;Dept.Chem.Technol.Energy Resources, East China Univ.Sci.& Technol., Shanghai 200237, China;Dept.Chem.Technol.Energy Resources, East China Univ.Sci.& Technol., Shanghai 200237, China
Abstract:With dilute hydrochloric acid as catalyst and promoted by ferrous chloride, hydrolysis of waste sawdust to produce monosaccharides was conducted by using an one-step method in a batch-wise operation reactor. Based on the model of first order consecutive irreversible reactions, the kinetics equation incorporating the term of catalyst concentration was obtained that is suitable for describing the hydrolysis of sawdust. Activation energies were calculated for hydrolysis of sawdust and decomposition of monosaccharides.
Keywords:sawdust  acid hydrolysis  inorganic acid  kinetics CLC No.:TK6 Document Code:A Article ID:1009606X(2004)01006405
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