| PE氯化原位接枝丙烯酸-2-羟基乙酯及丙烯酸丁酯制备热塑性弹性体的工业化及性能 |
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| 引用本文： | 唐量,张兆刚,宋志强,冯莺,赵季若.PE氯化原位接枝丙烯酸-2-羟基乙酯及丙烯酸丁酯制备热塑性弹性体的工业化及性能[J].山东化工,2010,39(12):1-3. |
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| 作者姓名： | 唐量 张兆刚 宋志强 冯莺 赵季若 |
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| 作者单位： | 青岛科技大学自动化与电子工程学院; |
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| 摘 要： | PE氯化原位接枝丙烯酸-2-羟基乙酯(CPE-cg-HEA)及丙烯酸丁酯(CPE-cg-BA)均具有优良综合物理力学性能。本文主要讨论CPE-cg-HEA及CPE-cg-BA工业化制备过程。在2m3搅拌反应釜中进行固相氯化原位接枝反应,在PE氯化同时进行接枝反应,最终将丙烯酸-2-羟乙酯及丙烯酸丁酯(HEA、BA)分别接枝到骨架聚合物氯化聚乙烯(CPE)上。对产物物理力学性能进行了测试,并分别与实验室制备的接枝物和商品CPE性能进行了比较。实验结果表明了接枝共聚物工业化的可行性,与CPE相比具有更好的综合性能。
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| 关 键 词： | CPE—cg—HEA CPE—cg—BA 制备 接枝共聚反应 工业化 |
Preparation and Properties of Thermoplastieity Elastomers in Industrialization - 2-hydroxy Ethylacrylate or Butylacrylate Grafted onto PE by in Situ Chlorinating-graft Copolymerization |
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| TANG Liang,ZHANG Zhao-gang,SONG Zhi-qiang,FENG Ying,ZHAO Ji-ruo.Preparation and Properties of Thermoplastieity Elastomers in Industrialization - 2-hydroxy Ethylacrylate or Butylacrylate Grafted onto PE by in Situ Chlorinating-graft Copolymerization[J].Shandong Chemical Industry,2010,39(12):1-3. |
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| Authors: | TANG Liang ZHANG Zhao-gang SONG Zhi-qiang FENG Ying ZHAO Ji-ruo |
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| Affiliation: | TANG Liang,ZHANG Zhao-gang,SONG Zhi-qiang,FENG Ying,ZHAO Ji-ruo(College of Automation Electronic Engineering,Qingdao University of Sci.& Tech.,Qingdao 266042,China) |
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| Abstract: | The graft copolymers(CPE-cg-HEA and CPE-cg-BA),including 2-hydroxy ethylacrylate(HEA) or butylacrylate(BA) grafted onto PE by in situ chlorinating-graft copolymerization,have excellent synthetical physical mechanical properties.The industrialization processes of CPE-cg-HEA and CPE-cg-BA were discussed.Solid-phase reaction of in-situ chlorinating graft copolymerization was proceeded in a agitated reactor(2m3),and 2-hydroxy ethyl arylate(HEA) and butyl acrylate(BA) were grafted onto polyethylene(PE) respectiv... |
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| Keywords: | CPE-cg-HEA CPE-cg-BA preparation graft copolymerization industrialization |
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