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Solutions of the general equations for the radiation dose dependence of the molecular weights of irradiated polymers with an initial Schulz-Zimm distribution
Authors:W Tim Bremner  Karen A Milne  James H O'Donnell
Affiliation:(1) Institute of Polymer Research, University of Waterloo, N2L 3G1, Ontario, Canada;(2) Polymer Materials and Radiation Group, Department of Chemistry, University of Queensland, 4072 Brisbane, Qld, Australia
Abstract:Summary The general equations for the radiation dose dependence of irradiated polymer molecular weights have been solved exactly. For an initial most probable molecular weight distribution (sgr=1), the solutions are analytical and exact. For the general case (sgrne1) the solutions are numerical and exact. The present approach has resulted in the solutions for both sgr=1 and sgrne1 being incorporated into a group of FORTRAN computer programs which will solve experimental data for scission and crosslinking yields by both minimization and exact treatments. Simulated data treated using these FORTRAN programs are give. The FORTRAN programs are available from the authors.
Keywords:
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