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Research on the Acidity of the Double-function Catalyst for DME Synthesis from Syngas
Authors:Ligang Wang  Yue Qi  Yingxu Wei  Deren Fang  Shuanghe Meng  Zhongmin Liu
Affiliation:(1) Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023, P. R. China;(2) Graduate School of Chinese Academy of Sciences, Beijing, 100039, P. R. China
Abstract:Two kinds of HZSM-5 zeolite (SiO2/Al2O3 = 50,300) were introduced into the STD (syngas-to-DME) reaction and the double-function catalysts containing CuO/ZnO/Al2O3 and HZSM-5 were investigated by activity evaluation and NH3-TPD. It was found that the acidity of HZSM-5 played a critical role in the performance of STD catalyst, and an appropriate acidic amount was required to obtain the best activity of STD catalyst; more and less acidic amount were both unfavorable for DME yield.
Keywords:syngas  dimethyl ether (DME)  methanol  SiO2/Al2O3 ratio  dehydration
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