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不同锌材的三价铬钝化效果
引用本文:杨娟平,郭瑞光,马建青.不同锌材的三价铬钝化效果[J].电镀与涂饰,2011,30(7):41-43.
作者姓名:杨娟平  郭瑞光  马建青
作者单位:1. 西安建筑科技大学环境与市政工程学院,陕西,西安,710055
2. 西安华佳表面涂饰有限公司,陕西,西安,710055
基金项目:国家自然科学基金项目,陕西省教育厅专项科研计划
摘    要:分别对纯锌片、钢铁镀锌片及含杂质锌片3种锌材进行三价铬钝化处理,钝化液组成及工艺条件为:硝酸铬50g/L,硝酸钠25~55 g/L,柠檬酸25~50 g/L,氯化钠70~80 g/L,硫酸钴25~50g/L,室温,pH 2.0,时间30~90 s.对比了不同锌材表面钝化膜的外观、金相形貌及耐蚀性等性能.结果表明,三价铬...

关 键 词:锌材  三价铬钝化  钝化膜  耐蚀性

Effect of zinc substrate on properties of trivalent chromium passive film
YANG Juan-ping,GUO Rui-guang,MA Jian-qing.Effect of zinc substrate on properties of trivalent chromium passive film[J].Electroplating & Finishing,2011,30(7):41-43.
Authors:YANG Juan-ping  GUO Rui-guang  MA Jian-qing
Affiliation:College of Environmental and Municipal Engineering,Xi’an University of Architecture and Technology,Xi’an 710055,China
Abstract:The pure zinc sheet,galvanized steel sheet and impure zinc sheet were separately treated by trivalent chromium passivation.The bath composition and operation conditions are as follows: chromic nitrate 50 g/L,sodium nitrate 25-30 g/L,citric acid 25-50 g/L,sodium chloride 70-80 g/L,cobaltous sulfate 25-50 g/L,room temperature,pH 2.0,and time 30-90 s.The appearance,metallographic morphology and corrosion resistance of passive films on different substrates were characterized and compared to each other.Results showed that the surface state and composition of zinc substrate influences coloring and corrosion resistance of passive film.The metal impurities produced during the passivation cause adverse effect on properties of passive film.
Keywords:zinc substrate  trivalent chromium passivation  passive film  corrosion resistance
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