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熔融接枝改性PVC树脂的研究
引用本文:樊文静,唐晓朝,揣成智. 熔融接枝改性PVC树脂的研究[J]. 塑料科技, 2009, 37(11)
作者姓名:樊文静  唐晓朝  揣成智
作者单位:天津科技大学材料科学与化学工程学院,天津,300457
摘    要:采用熔融接枝法制备了接枝聚氯乙烯(PVC)材料,研究了引发剂DCP、接枝单体MMA对PVC接枝物力学性能、耐热性、硬度及微观形态结构的影响。结果表明:接枝改性后PVC材料的力学性能、硬度均有所提高,具有较稳定的耐热性。在引发剂DCP用量为0.9%、接枝单体MMA用量为9%时,材料的综合性能达到最佳。

关 键 词:聚氯乙烯  甲基丙烯酸甲酯  熔融接枝  改性

Study on Modified PVC Resin by Melt Grafted Copolymerization
Fan Wenjing,Tang Xiaozhao,Chuai Chengzhi. Study on Modified PVC Resin by Melt Grafted Copolymerization[J]. Plastics Science and Technology, 2009, 37(11)
Authors:Fan Wenjing  Tang Xiaozhao  Chuai Chengzhi
Abstract:The grafted PVC material was prepared by melt grafting copolymerization. The effects of the content of initiator DCP and graft monomer on the mechanical properties,heat resistance,hardness and microscopic morphological structure of the PVC copolymer. The results indicated that the mechanical properties and hardness of the modified PVC material increased,and the heat resistance was stable. The comprehensive properties were optimal when the contents of monomer and initiator were 9% and 0.9% respectively.
Keywords:PVC   MMA   Melt grafted copolymerization   Modification
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