Crystallization of Li-Si-O-N oxynitride glasses |
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Authors: | H Unuma T Kokubo S Sakka |
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Affiliation: | (1) Institute for Chemical Research, Kyoto University, Uji, 611 Kyoto-Fu, Japan |
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Abstract: | Effects of nitrogen incorporation on the crystallization of a 3OLi2O · 70SiO2 glass have been studied in terms of the glass transition and crystallization temperatures, nucleation mechanism and precipitated crystalline phases. Glass transition and crystallization temperatures rise with increasing nitrogen content. Bulk crystallization is dominant in these oxinitride glasses. Precipitated crystallization phases and their relative amounts vary with nitrogen content. The experimental results are discussed assuming the formation of an ((-O-)3Si-)3N] unit and its evolution to an SiON3] unit in the residual glassy phase during the crystal growth.On leave from the Government Industrial Development Laboratory, Hokkaido, 2-17 Tsukisamu-Higashi, Toyohira-ku, Sapporo 004, Japan. |
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