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Preparation and characterization of soluble copoly(aryl ether ketone)s containing hindering structures
Authors:Yan Gao  Xigao Jian  Ying Dai  Junmin Xue  Shiming Peng  Shengjun Liu
Abstract:New copoly(aryl ether ketone)s have been synthesized by polycondensation of 2,2′,3,3′,6,6′‐hexaphenyl‐4,4′‐diphenol, 2,2′‐p‐hydroxyphenyl‐iso‐propane, and 4,4′‐difluorobenzophenone. The technology of 13C‐NMR was used to determine contents of the two bisphenols in the copolymers. Chain structure was characterized by illustrating average block length (LA, LC) in terms of portion of the triads (AKA, CKC, AKC). The obtained copoly(aryl ether ketone)s have the properties of excellent solubility, high heat‐resistance, good tensile strength, and good selectivity for gas permeability. © 2000 John Wiley & Sons, Inc. J Appl Polym Sci 78: 20–24, 2000
Keywords:polycondensation  copoly(aryl ether ketone)  chain structure  property  solubility
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