Abstract: | In this work, it was found that crosslinked chitosan (CCTS) had strong adsorption ability for some anions under certain conditions. Cr(VI) and Se(VI) existed in anion forms in aqueous solution, and their adsorption rates by CCTS were 97% for Cr(VI) at pH 3.0 and 95% for Se(VI) at pH 4.0. In addition, the adsorption balance time and isotherm of CCTS for Cr(VI) and Se (VI) were discussed and adsorption mechanism was explained. This research will be useful for designing CCTS‐based adsorption for metallic toxin removal and preconcentrating Cr(VI) and Se(VI) in their trace analysis. © 2000 John Wiley & Sons, Inc. J Appl Polym Sci 77: 3216–3219, 2000 |