Abstract: | Corrosion behaviour of Nd‐Fe‐B permanent magnets The corrosion behaviour of Nd‐Fe‐B permanent magnetic alloys as well as of single phases of these alloys have been investigated in sulphuric acid at room temperature and humid air at 150 °C using mass loss and electrochemical techniques. Scanning electron microscopy and scanning probe microscopy were used to study the surface topography. The electrostatic surface potential was examined by scanning probe microscopy using tapping mode. A correlation between the electrostatic surface potential and the corrosion rate of these alloys was found. The higher the value of the electrostatic surface potential of the intergranular phases the higher is the corrosion sensitivity. The strength of the corrosion attack on the phases of sintered permanent magnetic alloys is as follows: Ferrmagnetic phase < B‐rich phase < Nd‐rich phase. The differences in the chemical composition as well as in the preparation of these magnetic alloys have distinct influence on the corrosion resistance of the magnetic Nd‐Fe‐B alloys. |