| Abstract: | The fatty acid pattern was used to evaluate the alteration of a sunflower oil that had been used 20 times to fry various frozen foods with frequent replenishment (FR) or without replenishment (NR) of the used oil with fresh oil during frying. Furthermore, the fat extracted from potatoes fried in the sunflower oil from fryings 1, 5, 8, 12, 16 and 20 was also analysed by gas–liquid chromatography to compare its fatty acid profile with that of the corresponding fryer oil. The amount of unaltered fatty acids decreased from 96.2 mg per 100 mg oil in the unused sunflower oil to 89.6 mg per 100 mg oil after 20 fryings in the FR oil and to 88.9 mg per 100 mg oil in the NR oil, following a linear adjustment (r > 0.97; p < 0.001). Linoleic acid also decreased while palmitic and oleic acids increased in the bath oil. Fatty acid variations were more pronounced in NR than FR oil for major fatty acids and not only related to the degradation of unsaturated fatty acids but also to the interactions between the bath oil and the fried food fat. Thus the increase in palmitic acid of the fryer oil could be due to migration of this fatty acid from the prefried frozen potatoes as revealed by the composition of the fat extracted from those potatoes. Although the fatty acid variation (eg myristic, palmitic, oleic, trans–cis isomers of linoleic and linoleic acids) was not equivalent in FR or NR fryer oil and in the fat of the potatoes, the changes in total unaltered fatty acids were not significantly different in oil and potatoes. Present data suggest that frequent addition of fresh oil throughout the frying process minimises the fatty acid changes, contributing to the obtainment of fried foods with a healthy fatty acid profile. © 2000 Society of Chemical Industry |
