Abstract: | The viscosity properties of homogeneous polyelectrolyte complex solutions of sodium carboxymethyl cellulose (CMC) and poly(acrylamide‐co‐dimethyldiallylammonium chloride) have been investigated by means of a rotation viscometer at different complexation ratios, shear rates and temperatures. Compared with aqueous solutions of the component polyelectrolytes, such complex solutions can afford substantially increased viscosities at the complexation ratios examined, together with enhanced shear‐thinning rheology and temperature stability. According to this study, it is possible to improve the viscosity properties of water‐soluble polymers by homogeneous interpolyelectrolyte complexation in aqueous solutions. © 2000 Society of Chemical Industry |