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Rheology of cellulosic N‐methylmorpholine oxide monohydrate solutions
Authors:S Petrovan  J R Collier  G H Morton
Abstract:Shear dynamic and elongational rheology of concentrated solutions of cellulose in N‐methylmorpholine oxide monohydrate (lyocell) were investigated at different temperatures and for two Hencky strains. Shear thinning and strain thinning behavior is characteristic for dynamic viscosity and effective elongational viscosity of lyocell solutions. Body forces, enthalpy, and entropy of orientation are high at low temperature and high deformation rates, showing a strong orientation effect. © 2000 John Wiley & Sons, Inc. J Appl Polym Sci 77: 1369–1377, 2000
Keywords:lyocell solution  effective elongational viscosity  shear viscosity  dynamic moduli  entropy of orientation
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