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新型含硫缓蚀剂的制备及其缓蚀吸附行为
引用本文:杨光宏,刘东,丁一刚,查树义,杨昌炎. 新型含硫缓蚀剂的制备及其缓蚀吸附行为[J]. 武汉工程大学学报, 2012, 34(6): 18-21,26
作者姓名:杨光宏  刘东  丁一刚  查树义  杨昌炎
作者单位:1. 武汉工程大学绿色化工过程教育部重点实验室,新型反应器与绿色化学工艺湖北省重点实验室,湖北武汉430074
2. 湖北迅达药业股份有限公司,湖北武穴,435400
摘    要:以右旋磷霉素左旋苯乙胺盐为起始原料制得新型含硫缓蚀剂HEHSP-(Na)2,采用失重法和电化学极化法对其缓蚀效率进行了评价,探讨了其在Q235钢上的吸附行为.结果表明:HEHSP-(Na)2属于混合型缓蚀剂,在盐酸介质中缓蚀作用良好,其吸附符合Flory-Huggins等温方程,是多分子层吸附,属于物理吸附.

关 键 词:缓蚀剂  缓蚀效率  吸附

Preparation and inhibition adsorption behavior of new corrosion inhibitor containing sulfur
Yang Guang-hong , Liu Dong , Ding Yi-gang , Zha Shu-yi , Yang Chang-yan. Preparation and inhibition adsorption behavior of new corrosion inhibitor containing sulfur[J]. Journal of Wuhan Institute of Chemical Technology, 2012, 34(6): 18-21,26
Authors:Yang Guang-hong    Liu Dong    Ding Yi-gang    Zha Shu-yi    Yang Chang-yan
Affiliation:1(1.Key Lab for Green Chemical Process of Ministry of Education,Key Lab for Novel Reactors and Green Chemical Technology of Hubei Province,Wuhan Institute of Technology,Wuhan 430074,China;2.Hubei Xunda Pharmaceutical Co.,LTD,Wuxue 435400,China)
Abstract:Dextrofosfomysin levophenethylamine salt was used as the outset raw material to prepare HEHSP-(Na)2,a new corrosion inhibitor containing sulfur.The inhibition efficiency of HEHSP-(Na)2 was tested by weight loss and electrochemistry polarization methods.And the absorbance of HEHSP-(Na)2 on Q235 carbon steel was preliminarily discussed.The results show that HEHSP-(Na)2,as a complex inhibitor,gives nice inhibition efficiency on Q235 carbon steel in hydrochloric acid medium,its adsorption conforms to Flory-Huggins uniform temperature equation,which is multi-molecular layer layer adsorption,and belongs to physical adsorption.
Keywords:corrosion inhibitor  inhibition efficiency  adsorption
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