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电沉积Ni-Mo-P合金及其析氢电催化性能的研究
引用本文:李聪,许洪胤,杜朝军,郑盛会.电沉积Ni-Mo-P合金及其析氢电催化性能的研究[J].电镀与环保,2005,25(1):10-11.
作者姓名:李聪  许洪胤  杜朝军  郑盛会
作者单位:江西理工大学,江西,赣州,341000;金锋制品厂,广东,深圳,518000
摘    要:在大量文献的基础上,采用正交试验优化电沉积Ni-Mo-P合金工艺.经过测试证明:Ni-Mo-P合金镀层致密,结合力强,具有较高的硬度和耐高温腐蚀的性能.通过极化曲线的测定,钛基Ni-Mo-P合金具有比钛电极和铁电极更低的析氢过电势,Ni-Mo-P合金具有较高的电催化性能,可望成为新一代氯碱工业用高活性阴极.

关 键 词:Ni-Mo-P合金  电沉积  电催化
文章编号:1000-4742(2005)01-0010-02
修稿时间:2004年7月26日

A Study of Ni-Mo-P Alloy Electrodeposition and Its Electro-catalytic Properties for Hydrogen Evolution
LI Cong,XU Hong-yin,DU Chao-jun,ZHENG Sheng-hui.A Study of Ni-Mo-P Alloy Electrodeposition and Its Electro-catalytic Properties for Hydrogen Evolution[J].Electroplating & Pollution Control,2005,25(1):10-11.
Authors:LI Cong  XU Hong-yin  DU Chao-jun  ZHENG Sheng-hui
Abstract:Based on lots of references, Ni-Mo-P alloy is electrodeposited through orthogonal experiments. The tests show that the electrodeposited Ni-Mo-P alloy coating is compact in structure, strong in bonding strength, and had a higher hardness and corrosion resistance at high temperature. The polarization curves indicate that the overpotential of hydrogen evolution of Ti based Ni-Mo-P alloys is lower than that of Ti and Fe electrodes, which proves that Ni-Mo-P alloy has higher electro-catalytic properties, with a great potential to become an activating cathode of new generation for chlorine-alkali industry.
Keywords:Ni-Mo-P alloy  electrodeposition  electro-catalytic
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