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The Correlation between the Thermodynamic Functions of Molten Binary Systems of Alkali Metals
Authors:EE Shpil'rain  SN Skovorod'ko  AG Mozgovoi
Affiliation:(1) Russian Academy of Sciences, Institute of High Temperatures, Moscow, 125412, Russia
Abstract:Differential thermodynamic equations are used to reveal, in the general form, the correlation between some excess thermodynamic functions of liquid solutions. It is demonstrated that a certain correlation is observed in wide ranges of temperature and concentrations between the calculation and experimental data on excess molar enthalpy and specific volume of molten Na-K and K-Cs systems.
Keywords:differential thermodynamic equations  calculation and experimental data  molar enthalpy and specific volume
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